Originally Posted by
m_bisson
That's not how gas works. Sadly, it's all in your head.
The octane rating is actually an "anti-knock index" number. It has to do with how well a gas resists knocking, which is basically premature ignition due to high compression. That's why sports cars with turbo chargers, or some larger engines, need higher octane fuel. The pressure inside the combustion chamber is much higher, and 87 would ignite prematurely rather than with the spark plug.
You don't get more "octane" in 91 vs 87. The amount of energy produced per litre of fuel is actually the same.
The only possible explanation is if you're buying ethanol-free 91, and your 87 has ethanol, then you might see more mileage. Save some money and just use 87.